Accompanies manuscript: Chem. Sci. 2024 , Accepted Article . DOI: 10.1039/D4SC03005B. Raw data for the XRD, NMR, UV-Vis-NIR, and ATR-IR characterization. Raw input and output fil
The first structurally, spectroscopically, and electronically characterized metal-spiroligomer complexes are reported. The binuclear [M2L2]4+ ions (M = Mn, Zn) are macrocyclic “squares” and are charac
The coordination of acetonitrile and water to the Hg atom in [Hg(closo-1-CB11F11)2]2− (1) reveals the Lewis acidity of the HgII center, which is unprecedented, since 1 is a dianion. Both coordination
The synthesis and anion binding properties of novel halogen-bonding (XB) bis-iodotriazole-pyridinium-containing acyclic and [2]catenane anion host systems are described. The XB acyclic receptor displ