Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from Preformed Complexes [(TMS)<sub>2</sub>N]<sub>3</sub>Ln(μ-Cl)Li(THF)<sub>3</sub> (Ln = Pr, Nd, Sm; (TMS)<sub>2</sub>N = Bis(trimethylsilyl)amide)
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The complex [{(TMS)2N}4(μ4-Cl)Sm4(μ-SPh)4(μ3-Cl)Li(THF)] has been formed by protonolysis of [(Me3Si)2N]3Sm(μ-Cl)Li(THF)3 with 1 equiv of HSPh, which contains a square array of Sm(III) ions connected by a central μ4-Cl ligand. The edges of the square Sm4 array are bridged by four μ3-Cl and four μ-SPh ligands. The four Sm atoms and Li atom are connected by four μ3-Cl ligands.
创建时间：
2016-05-06
