Acyl-isothiocyanates as Efficient Thiocyanate Transfer Reagents
收藏NIAID Data Ecosystem2026-03-06 收录
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An unprecedented transfer of a thiocyanate (−SCN) group from aroyl/acyl isothiocyanate to alkyl or benzylic bromide is observed in the presence of a tertiary amine. This process is most effective when the bromomethyl proton is less acidic, while the presence of a more acidic proton gives 1,3-oxathiol-2-ylidine and other related products.
创建时间：
2009-08-06
