Ru-Catalyzed <i>Meta</i>-C–H Benzylation of Arenes with Toluene Derivatives
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The Ru-catalyzed meta-C–H benzylation of arenes bearing pyridyl, pyrimidyl, and pyrazolyl directing groups with toluene derivatives has been reported. Heptafluoroisopropyl iodide (iC3F7I) was employed as both a mild oxidant and radical initiator. This reaction showed excellent site-selectivity and tolerated a wide range of functional groups, providing a new strategy for the synthesis of various diarylmethane moieties.
创建时间：
2017-07-19
