Novel Carbon Monochalcogenide Coordination Mode: [Rh2{μ-SeCMo(CO)2(Tp)}2(η4-cod)2] (Tp = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)

Figshare2016-02-21 更新2026-04-29 收录

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https://figshare.com/articles/dataset/Novel_Carbon_Monochalcogenide_Coordination_Mode_Rh_sub_2_sub_SeCMo_CO_sub_2_sub_Tp_sub_2_sub_sup_4_sup_cod_sub_2_sub_Tp_hydrotris_3_5_dimethylpyrazol_1_yl_borate_cod_i_cyclo_i_octa_1_5_diene_/2537470

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资源简介：

The reaction of [Et4N][Mo(CSe)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [Rh2(μ-Cl)2(η4-cod)2] (cod = cyclo-octa-1,5-diene) results in the formation of the tetrametallic complex [Rh2{SeCMo(CO)2(Tp*)}2(η4-cod)2] in which the CSe ligand adopts a crystallographically confirmed and unprecedented μ3:σ,σ′(Se),σ″(C) coordination mode.

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2016-02-21

Novel Carbon Monochalcogenide Coordination Mode: [Rh2{μ-SeCMo(CO)2(Tp*)}2(η4-cod)2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)

Novel Carbon Monochalcogenide Coordination Mode: [Rh2{μ-SeCMo(CO)2(Tp)}2(η4-cod)2] (Tp = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)