<i>m</i><i>er</i>-[Fe(pcq)(CN)<sub>3</sub>]<sup>-</sup>: A Novel Cyanide-Containing Building Block and Its Application to Assembling Cyanide-Bridged Trinuclear Fe<sup>III</sup><sub>2</sub>Mn<sup>II</sup> Complexes [pcq<sup>-</sup> = 8-(Pyridine-2-carboxamido)quinoline Anion]
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数据链接：
https://figshare.com/articles/dataset/_i_m_i_i_er_i_Fe_pcq_CN_sub_3_sub_sup_sup_A_Novel_Cyanide_Containing_Building_Block_and_Its_Application_to_Assembling_Cyanide_Bridged_Trinuclear_Fe_sup_III_sup_sub_2_sub_Mn_sup_II_sup_Complexes_pcq_sup_sup_8_Pyridine_2_carboxamido_quinoline_Anion_/3250231数据链接链接失效反馈
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资源简介：
A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)(CN)3]2[Mn(CH3OH)2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]·CH3OH·2H2O (3), and [Fe(pcq)(CN)3]2[Mn(phen)2]·CH3OH·2H2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.
创建时间：
2016-05-05
