Stereocontrolled Construction of Either Stereoisomer of 12-Oxatricyclo[6.3.1.0<sup>2,7</sup>]dodecanes Using Prins−Pinacol Reactions
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12-Oxatricyclo[6.3.1.02,7]dodecanes can be efficiently synthesized in a stereoselective manner by Prins−pinacol reactions. By biasing the transition state of the Prins cyclization, it is possible to access either stereoisomer of this oxatricyclic ring system.
创建时间:
2016-05-06



