Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
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https://figshare.com/articles/dataset/Construction_of_Ultrastable_Porphyrin_Zr_Metal_Organic_Frameworks_through_Linker_Elimination/2354110
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资源简介：
A series of highly
stable MOFs with 3-D nanochannels, namely PCN-224
(no metal, Ni, Co, Fe), have been assembled with six-connected Zr6 cluster and metalloporphyrins by a linker-elimination strategy.
The PCN-224 series not only exhibits the highest BET surface area
(2600m2/g) among all the reported porphyrinic MOFs but
also remains intact in pH = 0 to pH = 11 aqueous solution. Remarkably,
PCN-224(Co) exhibits high catalytic activity for the CO2/propylene oxide coupling reaction and can be used as a recoverable
heterogeneous catalyst.
创建时间：
2013-11-13
