Carbon−Carbon Bond Formation on a Bis(oxazolinyl)phenyl−Rhodium Complex in a Reduction and Oxidative Addition Sequence
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下载链接：
https://figshare.com/articles/dataset/Carbon_Carbon_Bond_Formation_on_a_Bis_oxazolinyl_phenyl_Rhodium_Complex_in_a_Reduction_and_Oxidative_Addition_Sequence/3052561
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资源简介：
The unique C−C bond formation reaction between
diisopropylamine and CH2Cl2 proceeding on a bis(oxazolinyl)phenyl rhodium complex (tBu-Phebox-dm)RhCl2(H2O) (1) was
discovered. The intermediary chloromethyl complex, (tBu-Phebox-dm)Rh(CH2Cl)Cl(NEt3), which was obtained by reaction
of 1 with CH2Cl2 in the presence of amine, underwent C−C
bond formation with imine to give an azarhodacyclopentene
complex, 2.
创建时间：
2016-02-29
