Palladium Complexes of Chiral Planar 1-Phosphino-2-sulfenylferrocenes as Efficient Catalysts in Enantioselective Diels−Alder Reactions
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https://figshare.com/articles/dataset/Palladium_Complexes_of_Chiral_Planar_1_Phosphino_2_sulfenylferrocenes_as_Efficient_Catalysts_in_Enantioselective_Diels_Alder_Reactions/3301423
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资源简介：
The readily available dichloride palladium complexes of chiral planar (R)-1-phosphino-2-sulfenylferrocenes (Fesulphos ligands) act as efficient Lewis acids in the catalytic asymmetric
Diels−Alder reaction of cyclopentadiene with acryloyl-1,3-oxazolidin-2-one. Very high
enantioselectivities, up to 95% ee, have been reached from Fesulphos ligands having a very
bulky substitution at both sulfur and phosphorus coordinating atoms.
创建时间：
2005-02-14
