Metal-Free Hydrogenation of N‑Based Heterocycles
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Metal-free hydrogenation of substituted pyridines, quinolines, and several other N-heterocycles is achieved upon treatment of the nitrogen-based Lewis base with an equivalent of the Lewis acid B(C6F5)3 and H2 (4 atm) at 115 °C, to afford the ammonium-[HB(C6F5)3] salts of the reduced N-heterocycles.
创建时间:
2016-02-19



