[BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_BMIm_sub_4_sub_Sn_sub_9_sub_Se_sub_20_sub_Ionothermal_Synthesis_of_a_Selenidostannate_with_a_3D_Open_Framework_Structure/2617438
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资源简介：
The reaction of [K4(H2O)4][SnSe4] with [BMIm][BF4] at 130–180 °C afforded [BMIm]4[Sn9Se20] (1). The anion of the title compound represents a unique three-dimensional (3D) open framework, based on a variety of interconnectivity modes of Sn/Se units that lead to a system of six intersecting channels. 1 comprises the first example of a binary 3D open-framework selenidostannate anion and the first 3D open-framework chalcogenido metalate to be conveniently obtained by ionothermal synthesis.
创建时间：
2016-02-23
