Synthesis of New Chiral N-Heterocyclic Carbene−Imine Ligands and Their Application to an Asymmetric Allylic Alkylation Reaction
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https://figshare.com/articles/dataset/Synthesis_of_New_Chiral_N_Heterocyclic_Carbene_Imine_Ligands_and_Their_Application_to_an_Asymmetric_Allylic_Alkylation_Reaction/3361633
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资源简介:
Silver(I) and palladium(II) complexes of new
chiral N-heterocyclic carbene (NHC)−imine ligands
derived from trans-1,2-diaminocyclohexane have been
prepared. These ligands have been applied to a palladium(II)-catalyzed asymmetric allylic alkylation reaction
giving a maximum ee of 92%.
创建时间:
2016-05-07



