Novel Triple-Decker Sandwich Complex with a Six-Membered [B3Co2(μ4‑Te)] Ring as the Middle Deck
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Thermolysis of nido-[(Cp*Mo)2B4TeClH5], with an excess of Co2(CO)8 at room temperature, afforded a triple-decker sandwich complex [(Cp*Mo)2{μ-η6:η6-B3H3TeCo2(CO)5}] (4), which represents an unsaturated 24-valence-electron sandwich cluster in which the middle deck is composed of B, Co, and a heavy group 16 element.
创建时间:
2016-02-19



