The [2 + 4] Diels−Alder Cycloadditon Product of a Probable Dialuminene, Ar‘AlAlAr‘ (Ar‘ = C<sub>6</sub>H<sub>3</sub>- 2,6-Dipp<sub>2</sub>; Dipp = C<sub>6</sub>H<sub>3</sub>-2,6-Pr<sup>i</sup><sub>2</sub>), with Toluene
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Reduction of Ar‘AlI2 (Ar‘ = Ar‘= C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with KC8 in diethyl ether most probably affords the first “dialuminene”, Ar‘AlAlAr‘; it was characterized by its reaction with toluene which yielded a [2 + 4] cycloaddition product incorporating the Ar‘AlAlAr‘ unit.
创建时间:
2016-08-18




