Synthesis and Crystallographic Characterization of Chiral Bis-oxazoline-amides. Fine-Tunable Ligands for Pd-Catalyzed Asymmetric Alkylations
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https://figshare.com/articles/dataset/Synthesis_and_Crystallographic_Characterization_of_Chiral_Bis_oxazoline_amides_Fine_Tunable_Ligands_for_Pd_Catalyzed_Asymmetric_Alkylations/3064291
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资源简介：
New chiral chelating C2 bis-oxazoline-amide ligands (1) exhibiting a highly flexible molecular structure
have been prepared in high yield through a versatile synthetic pathway. Combined crystallographic, variable
temperature (VT)-NMR, IR, and ESI-MS studies have been carried out to investigate the nature of the
1−Pd complexes that are effective tools in controlling the stereochemical outcome of Pd-catalyzed allylic
alkylations (ee up to 98%).
创建时间：
2006-08-18
