Data_Sheet_1_A Highly Selective Perylenediimide-Based Chemosensor: “Naked-Eye” Colorimetric and Fluorescent Turn-On Recognition for Al3+.docx

A novel “turn-on” fluorescent probe (PCN) was designed, synthesized, and characterized with perylene tetracarboxylic disimide as the fluorophore and Schiff base subunit as the metal ion receptor. The probe demonstrated a considerable fluorescence enhancement in the presence of Al3+ in DMF with high selectivity and sensitivity. Furthermore, the considerably “off–on” fluorescence response simultaneously led to the apparent color change from colorless to brilliant yellow, which could also be identified by naked eye easily. The sensing capability of PCN to Al3+ was evaluated by the changes in ultraviolet–visible, fluorescence, Fourier transform–infrared, proton nuclear magnetic resonance, and high-resolution mass spectrometry spectroscopies. The linear concentration range for Al3+ was 0–63 μM with a detection limit of 0.16 μM, which allowed for the quantitative determination of Al3+.