Chiral Polycyclic Ketones via Desymmetrization of Dihaloolefins
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https://figshare.com/articles/dataset/Chiral_Polycyclic_Ketones_via_Desymmetrization_of_Dihaloolefins/3005401
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资源简介：
3-Chloronorbornenone (R)-1a (98% ee) was obtained from
trichloronorbornene 5 in two steps by the in situ generation
of dichloronorbornadiene 2a with t-BuOK and desymmetrization with (−)-ephedrine, followed by hydrolysis with
PPTS. The generality of this desymmetrization with (−)-ephedrine was tested with dibromonorbornadiene 2c and
other substituted dichloronorbornadienes.
创建时间：
2016-02-29
