Organoplatinum Complex Promoted the Asymmetric <i>Endo</i> Stereochemically Controlled Diels−Alder Reaction between 3-Diphenylphosphinofuran and Diphenylvinylphosphine
收藏NIAID Data Ecosystem2026-03-06 收录
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The organoplatinum complex containing ortho-metalated (R)-(1-(dimethylamino)ethyl)-naphthalene as the chiral auxiliary has been used efficiently to promote the asymmetric [4 + 2] Diels−Alder reaction between diphenylvinylphosphine and 3-diphenylphosphinofuran to generate two chelating diphosphine endocycloadducts in the ratio 17:1. The absolute configurations of the three newly generated stereocenters have been assigned by single-crystal X-ray analysis.
创建时间：
2016-02-25
