Novel Tin-Containing Crown Ether Substituted Ferrocenophanes as Redox-Active Hosts for the Ditopic Complexation of Lithium Chloride
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https://figshare.com/articles/dataset/Novel_Tin_Containing_Crown_Ether_Substituted_Ferrocenophanes_as_Redox_Active_Hosts_for_the_Ditopic_Complexation_of_Lithium_Chloride/2362447
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资源简介：
The synthesis is reported of the
crown ether substituted tin-containing
ferrocenophanes fc(SiMe2CH2)2Sn(X)CH2CH(CH2OC2H4OCH2)2 (1, X = Ph; 2, X = I; 3, X = Cl; 4, X = F) and of the ditopic complex 3·LiCl. The compounds were characterized by multinuclear
NMR spectroscopy, single-crystal X-ray diffraction analysis, and cyclic
voltammetry. DFT calculations revealed important two-electron stabilization
in 3 and 4 due to intramolecular O→Sn
coordination that is absent in 2.
创建时间：
2016-02-18
