Unexpected Catalytic Reactions of Silyl-Protected Enol Diazoacetates with Nitrile Oxides That Form 5-Arylaminofuran-2(3H)-one-4-carboxylates
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https://figshare.com/articles/dataset/Unexpected_Catalytic_Reactions_of_Silyl_Protected_Enol_Diazoacetates_with_Nitrile_Oxides_That_Form_5_Arylaminofuran_2_3_i_H_i_one_4_carboxylates/2553748
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资源简介：
Silyl-protected enol diazoacetates undergo dirhodium(II)-catalyzed reactions with nitrile oxides to form acid-labile ketenimines via dipolar cycloaddition of nitrile oxides to a donor/acceptor cyclopropene and Lossen rearrangement of the dipolar adduct; acid catalysis converts the ketenimine to the furan product.
创建时间：
2016-02-22
