Borole Formation by 1,1-Carboboration
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https://figshare.com/articles/dataset/Borole_Formation_by_1_1_Carboboration/2334523
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资源简介:
Bis(trimethylsilylethynyl)diphenylaminoborane
was reacted with the strong Lewis acid B(C6F5)3 at ambient temperature to give the borole 9 admixed with a small amount of its thermal follow–up
product 12. Compound 9 was subsequently
stabilized by adduct formation with pyridine (10). Treatment
of bis(trimethylsilylethynyl)phenylborane with B(C6F5)3 gave the borole 14, which reacted
with 3-hexyne to give the [4 + 2] cycloaddition product 15.
创建时间:
2016-02-18



