Entropy-Driven Ball-in-Bowl Assembly of Fullerene and Geodesic Phenylene Bowl
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https://figshare.com/articles/dataset/Entropy-Driven_Ball-in-Bowl_Assembly_of_Fullerene_and_Geodesic_Phenylene_Bowl/4877558
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资源简介:
Complexation of C60 at
a conical region of a nanometer-sized
geodesic phenylene bowl has been demonstrated. Proton NMR spectroscopy
showed formation of a 1:1 complex that was driven by entropy gains
for the assembly. Crystallographic analyses revealed its unique ball-in-bowl
structure, and the presence of smoothly curved surfaces was unveiled
at their interfaces.
创建时间:
2017-04-14



