Ethylene in Organic Synthesis: A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation
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https://figshare.com/articles/dataset/Ethylene_in_Organic_Synthesis_A_New_Route_to_Anticholenergic_Pyrrolidinoindolines_and_Other_Molecules_with_All_Carbon_Quaternary_Centers_via_Asymmetric_Hydrovinylation/2570971
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The asymmetric hydrovinylation (1 mol % Ni-cat., 1 atm, ethylene, >98% ee) products from 1-methylenetetralines are readily converted into 3,3-disubstituted oxindoles and subsequently to pyrrolidinoindolines. These hydrovinylation products are also useful for the syntheses of enantiopure benzomorphans.
创建时间:
2011-12-16



