Synthesis and X-ray Structure of a Highly Symmetrical Selenium-Centered Hexanuclear Neodymium Complex, [Cp<sup>t</sup><sub>6</sub>Nd<sub>6</sub>Se<sub>13</sub>]<sup>-</sup> (Cp<sup>t</sup> = η<sup>5</sup>-Bu<sup>t</sup>C<sub>5</sub>H<sub>4</sub>)<sup>†</sup>
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The half-sandwich tert-butylcyclopentadienyl neodymium complex [CptNdCl2(THF)2]2 (1) reacts with Na2Se5 to give organoneodymium polyselenide complex [Na(THF)6][Cpt6Nd6(μ6-Se)(μ2-Se2)6] (2), which has been characterized by X-ray crystallography.
创建时间：
2016-08-27
