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Mesoionic-Carbene-Stabilized Thiophosphoryl Cation (PS+)

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Figshare2021-04-28 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Mesoionic-Carbene-Stabilized_Thiophosphoryl_Cation_PS_sup_sup_/14509028
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The mesoionic carbene-stabilized PS+ cation 6 has been synthesized and first characterized by single-crystal X-ray diffraction analysis. Computational investigations reveal the typical multiple-bond character of the phosphorus–sulfur bond. A preliminary coordination investigation shows κ1 ligation with the S atom bonded to Cu­(I).
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2021-04-28
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