Mesoionic-Carbene-Stabilized Thiophosphoryl Cation (PS+)
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The mesoionic carbene-stabilized PS+ cation 6 has been synthesized and first characterized by single-crystal X-ray diffraction analysis. Computational investigations reveal the typical multiple-bond character of the phosphorus–sulfur bond. A preliminary coordination investigation shows κ1 ligation with the S atom bonded to Cu(I).
创建时间:
2021-04-28



