Reductive Disproportionation of Carbon Dioxide at an Iron(II) Center
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https://figshare.com/articles/dataset/Reductive_Disproportionation_of_Carbon_Dioxide_at_an_Iron_II_Center/2925346
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资源简介：
The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans-[Fe(dmpe)2(CO)H]·[HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32−. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy.
创建时间：
2008-07-28
