Reductive Disproportionation of Carbon Dioxide at an Iron(II) Center
收藏NIAID Data Ecosystem2026-03-06 收录
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The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans-[Fe(dmpe)2(CO)H]·[HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32−. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy.
创建时间：
2008-07-28
