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Synthesis of 2-Azaanthracenes via a Sequential Sonogashira Coupling/Alkynyl Imine−Allenyl Imine Isomerization/Aza-Diels−Alder/Elimination−Aromatization Reaction

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_2_Azaanthracenes_via_a_Sequential_Sonogashira_Coupling_Alkynyl_Imine_Allenyl_Imine_Isomerization_Aza_Diels_Alder_Elimination_Aromatization_Reaction/2694517
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An interesting sequential Sonogashira coupling/alkynyl imine−allenyl imine isomerization/aza-Diels−Alder/elimination−aromatization reaction, providing a facile synthesis of substituted 2-azaanthracenes from 1,6-diynes and imidoyl chlorides, is reported. The easy procedure accessing the products efficiently from readily available starting materials may imply a potential synthetic application.
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2016-02-23
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