The reaction of [{Cp(CO)2Fe}BiCl2] (1a) with [Co(CO)4]- leads to the formation of the first heteroleptic substituted bismuthane, [(μ3-Bi){Co(CO)4}2{Fe(CO)2Cp}] (2). When the “open” complex 2 is irradi
The attached data files are the full bioinformatics output for the first six soil samples collected during the University of St Andrews "Antibiotics under our feet" citizen science project funded by a
N-heterocyclic carbene complexes of ruthenium(II), [CpRu(L*)2Cl] (2) and [CpRu(CO)(L*)Cl] (3) (Cp = η5-C5H5; L* = 1,3-dicyclohexyl-imidazolin-2-ylidene), have been obtained in high yields by reaction
The reaction between [[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]Li(THF)3]2 and either Cp2Sn or Cp2Pb in toluene cleanly gives the compounds rac-[{Me2P(BH3)}(Me3Si)C{(SiMe2)(CH2)}]2E in moderate yield [E = Sn
We report the formation of phosphine-ligated alkylpalladium(II) amido complexes that undergo reductive elimination to form alkyl-nitrogen bonds and a combined experimental and computational investiga