Ammonium Octahydrotriborate (NH4B3H8): New Synthesis, Structure, and Hydrolytic Hydrogen Release
收藏Figshare2016-02-23 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Ammonium_Octahydrotriborate_NH_sub_4_sub_B_sub_3_sub_H_sub_8_sub_New_Synthesis_Structure_and_Hydrolytic_Hydrogen_Release/2662096
下载链接
链接失效反馈官方服务：
资源简介：
A metathesis reaction between unsolvated NaB3H8 and NH4Cl provides a simple and high-yield synthesis of NH4B3H8. Structure determination through X-ray single crystal diffraction analysis reveals weak N−Hδ+---Hδ−−B interaction in NH4B3H8 and strong N−Hδ+---Hδ−−B interaction in NH4B3H8·18-crown-6·THF adduct. Pyrolysis of NH4B3H8 leads to the formation of hydrogen gas with appreciable amounts of other volatile boranes below 160 °C. Hydrolysis experiments show that upon addition of catalysts, NH4B3H8 releases up to 7.5 materials wt % hydrogen.
创建时间：
2016-02-23
