Regioselective Dimetallapolycarbyl Hydrometalation
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https://figshare.com/articles/dataset/Regioselective_Dimetallapolycarbyl_Hydrometalation/3251149
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资源简介：
The reactions of [L(CO)2W⋮CC⋮CC⋮CC⋮W(CO)2L] (L = HB(pz)3, HB(pz‘)3; pz = pyrazol-1-yl, pz‘
= 3,5-dimethylpyrazol-1-yl) with [RuHCl(CO)(PPh3)3]
result in regioselective hydroruthenation of one C⋮C
bond of the WC6W spine to provide the coordinatively
unsaturated hex-2-en-4-yn-3-yl-1,6-diylidyne-bridged complex [Ru{C(C⋮CC⋮W(CO)2L)CHC⋮W(CO)2L}Cl(CO)(PPh3)2].
创建时间：
2016-05-05
