Dis-assembly of a Benzylic CF<sub>3</sub> Group Mediated by a Niobium(III) Imido Complex
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All three C–F bonds in CF3-substituted arenes are activated by a niobium imido complex, driven by the formation of strong Nb–F bonds. The mechanism of this transformation was studied by NMR spectroscopy, which revealed the involvement of Nb(III). Attempts to extend this chemistry to nonaromatic CF3 groups led to intramolecular reactivity.
创建时间：
2016-02-19
