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Bis[tetraruthenium(IV)]-Containing Polyoxometalates: [{RuIV4O6(H2O)9}2Sb2W20O68(OH)2]4– and [{RuIV4O6(H2O)9}2{Fe(H2O)2}2{β-TeW9O33}2H]−

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Figshare2016-02-20 更新2026-04-29 收录
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The reaction of [Sb2W22O74(OH)2]12– and [Fe4(H2O)10(β-TeW9O33)2]4– with (NH4)2[RuCl6] in aqueous solution resulted in the novel ruthenium­(IV)-containing polyanions [{RuIV4O6­(H2O)9}2­Sb2W20O68(OH)2]4– and [{RuIV4O6­(H2O)9}2­{Fe­(H2O)2}2­{β-TeW9O33}2H]−, exhibiting two cationic, adamantane-like, tetraruthenium­(IV) units {Ru4O6(H2O)9}4+ bound to the respective polyanion in an external, highly accessible fashion.

创建时间:
2016-02-20
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