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Palladacycle-Catalyzed Asymmetric Intermolecular Construction of Chiral Tertiary P-Heterocycles by Stepwise Addition of H–P–H Bonds to Bis(enones)

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https://figshare.com/articles/dataset/Palladacycle_Catalyzed_Asymmetric_Intermolecular_Construction_of_Chiral_Tertiary_P_Heterocycles_by_Stepwise_Addition_of_H_P_H_Bonds_to_Bis_enones_/2506927
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资源简介:
A palladacycle-catalyzed diastereo- and enantioselective stepwise double hydrophosphination of bis­(enones) with PhPH2 has been developed, allowing intermolecular construction of chiral tertiary bulky P-heterocycles in one pot in high yields. A catalytic cycle for the reaction is proposed as well.
创建时间:
2012-07-09
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