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Palladacycle-Catalyzed Asymmetric Intermolecular Construction of Chiral Tertiary P-Heterocycles by Stepwise Addition of H–P–H Bonds to Bis(enones)

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NIAID Data Ecosystem2026-03-07 收录
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A palladacycle-catalyzed diastereo- and enantioselective stepwise double hydrophosphination of bis­(enones) with PhPH2 has been developed, allowing intermolecular construction of chiral tertiary bulky P-heterocycles in one pot in high yields. A catalytic cycle for the reaction is proposed as well.

创建时间:
2012-07-09
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