Isolation of a 2‑Hydroxytetrahydrofuran Complex from Copper-Promoted Hydroxylation of THF
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https://figshare.com/articles/dataset/Isolation_of_a_2_Hydroxytetrahydrofuran_Complex_from_Copper_Promoted_Hydroxylation_of_THF/2391070
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资源简介：
A complex of a binucleating macrocyclic
ligand comprising a [CuII(μ-OH)Na]2+ core
reacts with CuI in THF/CH3CN to yield a novel species with
a deprotonated 2-hydroxytetrahydrofuran (THF-2-ol) bridging between
CuII and NaI ions. The complexes were characterized
by X-ray crystallography, electron paramagnetic resonance spectroscopy,
and electrospray ionization mass spectrometry. 18O-labeling
studies support incorporation of the O atom from μ-OH into the
coordinated THF-2-ol ligand.
创建时间：
2016-02-19
