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Transition metal ordering in LiNiO2 and its effect on the performance as cathode material in batteries

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ESRF Portal2028-01-01 更新2026-04-23 收录
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Layered oxides (LiMeO2, Me = Co, Ni, Mn) with the space group R-3m are state-of-the-art cathode materials in Li ion batteries. In these materials, Ni2+ is the redox-active centre, and the amount of Ni2+ limits the capacity. The amount, in turn, is a maximum of 1/3 of the Me 3a sites in the Me-O host structures. LiNiO2 is, with 33%, the material with the highest Ni2+ content. This work aims to unravel the origin of the Ni2+ content- and, thus the capacity-limitation of layered oxides.

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2028-01-01
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