Cleavage of the C(O)–S Bond of Thioesters by Palladium/Norbornene/Copper Cooperative Catalysis: An Efficient Synthesis of 2‑(Arylthio)aryl Ketones
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A Pd/norbornene/Cu cooperative catalysis for the efficient synthesis of 2-(arylthio)aryl ketones from aryl halides and thioesters has been developed. The first example of cooperative catalysis by palladium, norbornene, and copper, wherein the C(O)–S bond of thioesters is cleaved by a PdII palladacycle with the assistance of CuI, has been observed.
创建时间：
2016-06-17
