Alkylation Reactions of [WS<sub>4</sub>]<sup>2-</sup> and [(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)WS<sub>3</sub>]<sup>-</sup> with 2,6-Bis(bromomethyl)pyridine: The First Isolation of Bisalkylated Tetrathiometalate WS<sub>2</sub>{2,6-(SCH<sub>2</sub>)<sub>2</sub>(C<sub>5</sub>H<sub>3</sub>N)}
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数据链接：
https://figshare.com/articles/dataset/Alkylation_Reactions_of_WS_sub_4_sub_sup_2-_sup_and_sup_5_sup_-C_sub_5_sub_Me_sub_5_sub_WS_sub_3_sub_sup_-_sup_with_2_6-Bis_bromomethyl_pyridine_The_First_Isolation_of_Bisalkylated_Tetrathiometalate_WS_sub_2_sub_2_6-_SCH_sub_2_sub_sub_2_sub_C_sub_5_sub_H_/3607485数据链接链接失效反馈
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资源简介：
The trithio and tetrathio complexes of tungsten (PPh4)[Cp*WS3] (Cp* = η5-C5Me5) and (PPh4)2[WS4] undergo alkylation reactions with 2,6-bis(bromomethyl)pyridine to yield [(Cp*WS2)2{2,6-(SCH2)2(C5H3N)}]·CH3CN (1·CH3CN) (73.1% yield) and WS2{2,6-(SCH2)2(C5H3N)} (2) (76.0% yield), respectively. In the dinuclear complex 1, two Cp*WS3 units are linked by a 2,6-dimethylenepyridine bridge, and the pyridine nitrogen is not coordinated at tungsten. Complex 2 is the first example of bisalkylated tetrathiometalates, the mononuclear structure of which is stabilized by coordination of the pyridine nitrogen.
创建时间：
2016-08-17
