Unprecedented Homochiral Olefin−Copper(I) 2D Coordination Polymer Grid Based on Chiral Ammonium Salts as Building Blocks
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下载链接：
https://figshare.com/articles/dataset/Unprecedented_Homochiral_Olefin_Copper_I_2D_Coordination_Polymer_Grid_Based_on_Chiral_Ammonium_Salts_as_Building_Blocks/3361243
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资源简介：
4-Vinylbenzylcinchonidinium chloride ([VB-N-CIN]Cl; 1), prepared from the corresponding cinchona
alkaloid and 4-vinylbenzyl chloride in refluxing acetone
and N,N-dimethylformamide, solvothermally reacts with
CuICl to afford the unprecedented 2D homochiral copper(I)−olefin coordination polymer Cu5Cl6(VB-N-CIN)2·C2H5OH (2·EtOH) with a 2D layered network. A preliminary enantioseparation investigation shows that the
2D layered network in 2 is capable of selectively intercalating (R)-2-butanol.
创建时间：
2016-05-07
