Asymmetric Ketoalkylation/Rearrangement of Alkyenlfurans via Synergistic Photoredox/Brønsted Acid Catalysis
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https://figshare.com/articles/dataset/Asymmetric_Ketoalkylation_Rearrangement_of_Alkyenlfurans_via_Synergistic_Photoredox_Br_nsted_Acid_Catalysis/21378933
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资源简介:
An
enantioselective three-component rearrangement of alkenylfurans
with various cycloalkyl silyl peroxides and anilines has been developed
by merging photoredox catalysis with chiral Brønsted acid catalysis.
This protocol provides expedient access to a broad spectrum of ketoalkyl-functionalized
4-aminocyclopentenones in high yields with excellent enantio- and
diastereoselectivities. Diverse functional groups can be introduced
via facile product derivations.
创建时间:
2022-10-21



