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Molecular Supertetrahedron Decorated with Exposed Sulfonate Groups Built from Mixed-Valence Tetranuclear Fe<sub>3</sub><sup>3+</sup>Fe<sup>2+</sup>(μ<sub>3</sub>-Ο)(μ<sub>3</sub>-SO<sub>4</sub>)<sub>3</sub>(−CO<sub>2</sub>)<sub>3</sub> Clusters

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NIAID Data Ecosystem2026-03-06 收录
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We present the synthesis and characterization of a novel metal−organic molecular solid using the ligand 4,8-disulfonaphthalene-2,6-dicarboxylic acid. The solid features a sulfonated, isolated supertetrahedra, [Fe16Ο4(SO4)12(L2)6], built from mixed-valence [Fe33+Fe2+(μ3-Ο)(μ3-SO4)3(−CO2)3] clusters.

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2009-11-02
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