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A New S = 0 ⇄ S = 2 “Spin-Crossover” Scenario Found in a Nickel(II) Bis(nitroxide) System

Figshare2018-03-06 更新2026-04-29 收录

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https://figshare.com/articles/dataset/A_New_i_S_i_0_i_S_i_2_Spin-Crossover_Scenario_Found_in_a_Nickel_II_Bis_nitroxide_System/5952310 数据链接链接失效反馈

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A New S = 0 ⇄ S = 2 “Spin-Crossover” Scenario Found in a Nickel(II) Bis(nitroxide) System

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2018-03-06

分子磁性

配合物合成

Three new linear compounds of the type Co3(dpa)4X2, where dpa is the anion of di(2-pyridyl)amine and X is NCS- (5), CN- (6), and N(CN)2- (7), have been prepared, and their structures and magnetic beha

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Dinuclear Cu(II) Complexes of Isomeric Bis-(3-acetylacetonate)benzene Ligands: Synthesis, Structure, and Magnetic Properties

双核铜配合物

分子磁性

Highly versatile coordinating ligands are designed and synthesized with two β-diketonate groups linked at the carbon 3 through a phenyl ring. The rigid aromatic spacer is introduced in the molecules t

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Magnetic Exchange Coupling in Chloride-Bridged 5f−3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate Dimer

分子磁性

磁电耦合

The homoleptic dimer complex [U(Me2Pz)4]2 (Me2Pz− = 3,5-dimethylpyrazolate) was obtained upon reacting UCl4 with KMe2Pz in THF, followed by extraction into toluene. The structure of the dimer consists

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Synthesis, Structure, and Magnetic Properties of (A)[Fe III (oxalate)Cl 2 ] (A = Alkyl Ammonium Cations) with Anionic 1D [Fe III (oxalate)Cl 2 ] - Chains

配位化学

分子磁性

The use of alkyl ammonium cations resulted in four compounds of (A)[FeIII(ox)Cl2] (A = Et3NH+ (1a, 1b), Me4N+ (2), and n-Bu4N+ (3); ox = oxalate), whose structures and magnetic properties were charact

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Aryl-Containing Chelates and Amine Debenzylation to Afford 1,3-Di-2-pyridyl-2-azaallyl (smif): Structures of {κ-C,N,N py 2 -(2-pyridylmethyl) 2 N(CH 2 (4- t Bu-phenyl-2-yl))}FeBr and (smif)CrN(TMS) 2

杂金属配合物

分子磁性

Aryl-bromide ligand precursors have been prepared with the potential to afford tetradentate chelates (2-pyridylmethyl)3−xN(CH2-2-Aryl)x (x = 1, 2) containing metal-aryl linkages that promise to impart

NIAID Data Ecosystem50

A New S = 0 ⇄ S = 2 “Spin-Crossover” Scenario Found in a Nickel(II) Bis(nitroxide) System

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