Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for “Click” Coupling
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https://figshare.com/articles/dataset/Modular_Synthesis_of_Alkyne_Substituted_Ruthenium_Polypyridyl_Complexes_Suitable_for_Click_Coupling/2433445
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资源简介:
A modular synthetic method has been
developed for the preparation of Ru polypyridyl complexes bearing
a terminal alkyne. This method proceeds through a readily accessible
intermediate with a silyl-protected alkyne and allows access to a
variety of five- and six-coordinate Ru complexes. These complexes
can be easily attached to azide-functionalized electrode surfaces
with only slight perturbation of the redox properties of the parent
complex.
创建时间:
2016-02-19



