Enantioselective Nickel-Catalyzed Hydrocyanative Desymmetrization of Norbornene Derivatives
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https://figshare.com/articles/dataset/Enantioselective_Nickel-Catalyzed_Hydrocyanative_Desymmetrization_of_Norbornene_Derivatives/14755422
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资源简介：
A nickel-catalyzed
enantioselective hydrocyanation of N-aryl 5-norbornene-endocis-2,3-dicarboximides
was reported. This
desymmetrization process allows for a quick construction of both continuous
stereogenic carbon centers and remote N–CAr atropisomeric
chirality. Mechanism studies indicated that the resident carbonyl
group of the substrates plays a key role in the enantioselectivity.
创建时间：
2021-06-09
