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Luminescent MTN-Type Cluster–Organic Framework with 2.6 nm Cages

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Figshare2016-02-20 更新2026-04-29 收录
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From a basic tetrahedral Cu4I4 cluster, a new MTN-type cluster–organic framework (COZ-1) containing giant 64512 and 512 cages was successfully constructed. The 64512 cage has an inner diameter of 2.6 nm and a large pore volume of 9.2 nm3; these tetrahedral Cu4I4 clusters with bulky size offer new opportunities for not only the formation of 4-connected zeotype structures but also the integration of porosity and photoluminescent properties from both the cluster and the framework.

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2016-02-20
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