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The Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Ynones with Azomethine Ylides

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https://figshare.com/articles/dataset/The_Catalytic_Asymmetric_1_3_Dipolar_Cycloaddition_of_Ynones_with_Azomethine_Ylides/2618572
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资源简介:
The first catalytic asymmetric 1,3-dipolar cycloaddition of electron-deficient carbon–carbon triple bonds with azomethine ylides has been established. This reaction provides an unprecedented approach to access novel 2,5-dihydropyrrole derivatives with potential bioactivities in perfect enantioselectivities of up to >99% ee.
创建时间:
2011-09-02
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