Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl<sub>2</sub> Complexes That Exhibit High-Temperature H<sub>2</sub> Sorption and Chemical Reactivity
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Rational_Design_of_Porous_Coordination_Polymers_Based_on_Bis_phosphine_MCl_sub_2_sub_Complexes_That_Exhibit_High_Temperature_H_sub_2_sub_Sorption_and_Chemical_Reactivity/2362195
下载链接
链接失效反馈官方服务：
资源简介：
MCl2 complexes of a new p-carboxylated
1,2-bis(diphenylphosphino)benzene ligand are effectively utilized
as tetratopic building blocks to prepare isostructural porous coordination
polymers with accessible reactive metal sites (M = Pd, Pt). The crystalline
materials exhibit unusual and fully reversible H2 sorption
at 150 °C. Post-synthetic reactivity is also possible, in which
Pt–Cl bonds can be activated to provide organometallic species
in the pores.
创建时间：
2016-02-18
